Title: Optimized Adsorption of Had and OHad over Amorphous SrRuPtOxHy Nanobelts towards Efficient Alkaline Fuel Cell Catalysis

Authors: Siyu Liu, Shangheng Liu, Jingliang Bao, Zhongliang Huang, Licheng Wei, Nanjun Chen, Zhiwei Hu, Wei-Hsiang Huang, Chih-Wen Pao, Qingyu Kong, Jiajia Han, Leigang Li, Xiaoqing Huang*

Abstract: PtRu-based catalysts toward hydrogen oxidation reaction (HOR) suffer from low efficiency, CO poisoning and over-oxidation at high potentials. In this work, an amorphization strategy is adopted for preparation of amorphous SrRuPtOxHy nanobelts (a-SrRuPtOxHy NBs). The a-SrRuPtOxHy NBs have optimized adsorption of intermediates (H and OH), increased number of active sites, highly weakened CO poisoning and enhanced anti-oxidation ability owing to the special amorphous structure. Consequently, a-SrRuPtOxHy NBs displays superior HOR performance with a mass activity of 7.3 A/mgPt+Ru, 23 and 5 times of that of SrRuPt(OH)x NBs and commercial PtRu/C, respectively, and long-lasting stability. Besides, a peak power density of 750 mW/cm2 and a specific power of 14.8 W/mgPt+Ru have been achieved for a-SrRuPtOxHy NBs at a low loading of 0.05 mgPt+Ru/cm2, surpassing many reported HOR catalysts. Mechanism investigation indicates that Pt and Ru are present in oxide/hydroxide forms and H in a-SrRuPtOxHy NBs participates in HOR. Ab initio molecular dynamics (AIMD) simulations and density functional theory (DFT) calculations show that there are three catalytic mechanisms participating in a-SrRuPtOxHy NBs, which all exhibit low catalytic barrier and highly improved HOR efficiency. This work provids a new strategy for designing high-performance catalysts towards fuel cells.

Full-Link: https://onlinelibrary.wiley.com/doi/10.1002/anie.202421013