ISSN 1008-5548

CN 37-1316/TU

2020年26卷  第1期
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复配纳米催化剂在稠油降黏中的应用及其机理

Effects and mechanism of combined nano-catalysts on viscosity reduction of heavy oil

Doi:10.13732/j.issn.1008-5548.2020.01.011
作者:黄佳,江航,赵长虹,周明辉,赵慧龙,孙盈盈,邢向荣,吕柏林,樊铖

摘要:为探讨固体稠油的原位改质降黏技术,提高采收率,对其中关键因素催化剂进行研究。分别采用油溶性催化剂环烷酸铁与水溶性纳米催化剂硝酸铁,对新疆油田中的稠油固体进行改质降黏,并采用集总的分布式活化能模型(DAEM)模型对稠油固体热解过程进行分析。结果表明:环烷酸铁和硝酸铁独立作为催化剂时,对于稠油固体的降黏率分别到56. 29%、45. 40%;两者复配使用时,降黏率可达到97%,复配协同作用有助于集成各自优势。

关键词:稠油固体;催化降黏;复配催化剂;分布式活化能模型;热解动力学

Abstract: In order to study in-situ modification and viscosity reduction technology of solid heavy oil and improve oil recovery,the most critical factor catalyst was studied.Iron naphthenate,an oil-soluble catalyst,and ferric nitrate,a watersoluble catalyst,were employed,and their separate and combined effects on viscosity reduction were evaluated.The results showed that,the viscosity of heavy oil was reduced by 56.29% and 45.40% respectively when the two were used as separate catalyst,while the viscosity was significantly reduced by 97% when the two catalysts were combined.The distributed activation energy model ( DAEM) was employed to analyze the pyrolysis process of heavy oil and the synergistic effect of the catalysts helps to integrate the advantages of the two catalysts.

Keywords: heavy oil; viscosity reduction; combined catalyst; distributed activation energy model; dynamics