原晓菲a，钟 睿a，洪若瑜a，陈 剑b
(福州大学 a. 石油化工学院; b. 电气工程与自动化学院，福建 福州 350108)
DOI:10.13732/j.issn.1008-5548.2022.03.012
收稿日期： 2021-12-21， 修回日期：2022-04-21，在线出版时间：2022-05-06。
基金项目：中央引导地方科技发展专项项目，编号：2017L3014；福建省闽江学者奖励计划项目，编号：闽人社批复[2016]149号；福建省战略性新兴产业研发基金项目，编号：82918001；福建省新能源发电与电能变换重点实验室项目，编号：KLIF-202102。
第一作者简介：原晓菲(1997—)，女，硕士研究生，研究方向为石墨烯粉体的等离子体制备。E-mail: xiaof.yuan@qq.com。
通信作者简介：洪若瑜(1966—)，男，闽江学者特聘教授，博士，博士生导师，研究方向为纳米材料的制备与应用。E-mail: rhong@fzu.edu.cn。
摘要：综述等离子体自上而下和自下而上制备石墨烯粉体的方法，等离子体原位掺杂、后处理掺杂、刻蚀等石墨烯基材料改性工艺，石墨烯及掺杂石墨烯粉体在超级电容器、锂电池和电催化剂等领域应用。提出等离子体技术制备石墨烯粉体材料工艺具有简单快速、有效可控、环境友好等优势，可通过等离子体技术实现石墨烯表面功能化，以提高其电化学和电催化性能。认为开发等离子体法工艺对工业化生产石墨烯粉体具有积极意义，经等离子体法改性的石墨烯粉体材料可以拓宽石墨烯基粉体材料的应用领域。
关键词：等离子体；石墨烯；掺杂；电化学；电催化
Abstract：The methods of plasma top-down and bottom-up preparation of graphene powder, modification technology of plasma in-situ, plasma post-treatment adulteration and plasma etching of graphene-based materials, and the application of supercapacitors, lithium batteries and electrocatalysts of graphene and doped graphene powder were reviewed. It is proposed that the preparation of graphene powder materials by plasma technology is simple and rapid, effective and controllable, and environmentally friendly. The surface functionalization of graphene can be realized by plasma technology to improve its electrochemical and electrocatalytic properties.It is concluded that the development of plasma process is of positive significance to the industrial production of graphene powder, and the graphene powder materials modified by plasma can broaden the application field of graphene-based powder materials.
Keywords：plasma; graphene; heteroatom doping; electrochemistry; electrocatalysis
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