Microscopic Structure‐Property Relation of Metal‐Organic Polyhedron Nanocomposites
Release time:2019-09-26
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Indexed by:Journal paper
First Author:Mingxin Zhang
Correspondence Author:Caili Huang*, Panchao Yin*
Co-author: Yuyan Lai, Mu Li, Tao Hong, Weiyu Wang, Haitao Yu, Lengwan Li, Qianjie Zhou, Yubin Ke, Xiaozhi Zhan, Tao Zhu, Caili Huang,*,Panchao Yin*
Journal:Angewante Chemie International Edition
Included Journals:SCI
Document Type:J
Volume:58
Page Number:17412–17417
Date of Publication:2019-09-23
Abstract:Monodispersed hairy nanocomposites system with typical 2‐nm (isophthalic acid) 24 Cu 24 metal‐organic polyhedron (MOP) as core protected by 24 polymer chains with controlled narrow molecular weight distribution has been experimentally probed by imaging and scattering studies for the heterogeneity of polymers in the nanocomposites and the confinement effect the MOPs imposing to anchored polymers. Typical confined‐extending surrounded by one entanglement area is proposed to picture the physical states of polymer chains. This model dictates the counterintuitive thermal and rheological properties
Links to published journals:https://onlinelibrary.wiley.com/doi/10.1002/anie.201909241
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