闫颖洁、廖綦楠同学（胡真虎研究组）在国际刊物发表论文

我系胡真虎教授研究组研究生闫颖洁、廖綦楠同学题为“Decomposition of 3,5-dinitrobenzamide in aqueous solution during UV/H₂O₂ and UV/TiO₂ oxidation processes” 的论文被国际期刊《Environmental Science and Pollution Research》接收发表。摘要如下：

3,5-dinitrobenzamide has been widely used as a feed additive to control coccidiosis in poultry, and part of the added 3,5-dinitrobenzamide is excreted into wastewater and surface water. The removal of 3,5-dinitrobenzamide from wastewater and surface water has not been reported in previous studies. Highly reactive hydroxyl radicals from UV/H₂O₂ and UV/TiO₂ advanced oxidation processes (AOPs) can decompose organic contaminants efficiently. In this study, the decomposition of 3,5-dinitrobenzamide in aqueous solution during UV/H₂O₂ and UV/TiO₂ oxidation processes was investigated. The decomposition of 3,5-dinitrobenzamide fits well with a fluence-based pseudo-first-order kinetics model. The decomposition in both two oxidation processes was affected by solution pH, and was inhibited under alkaline conditions. Inorganic anions such as NO^3-, Cl^-, SO₄^2-, HCO₃^- and CO₃^2- inhibited the degradation of 3,5-dinitrobenzamide during the UV/H₂O₂ and UV/TiO₂ oxidation processes. After complete decomposition in both oxidation processes, approximately 50% of 3,5-dinitrobenzamide was decomposed into organic intermediates, and the rest was mineralized to CO₂, H₂O and other inorganic anions. Ions such as NH₄⁺, NO₃^-, and NO₂^- were released into aqueous solution during the degradation. The primary decomposition products of 3,5-dinitrobenzamide were identified using time-of-flight mass spectrometry (LCMS-IT-TOF). Based on these products and ions release, a possible decomposition pathway of 3,5-dinitrobenzamide in both UV/H₂O₂ and UV/TiO₂processes was proposed.

论文链接：http://link.springer.com/article/10.1007/s11356-016-8245-1